M. MAKOUF Naouel

MCB

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Department

Departement of Chemistry

Research Interests

Specialized in Departement of Chemistry. Focused on academic and scientific development.

Contact Info

University of M'Sila, Algeria

Email : naouel.makouf@univ-msila.dz

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Recent Publications

2019-01-25

Diaquabis[4-(dimethylamino)pyridine-jN1]bis[2- (1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)acetatojO 1]cobalt(II)

In the mononuclear title complex, [Co(C10H6NO4)2(C7H10N2)2(H2O)2], the CoII ion is located on an inversion centre and has a distorted octa­hedral coordination geometry of type CoN2O4 by two N atoms from the two 4-(di­methyl­amino)­pyridine (DMAP) ligands, two carboxyl­ate O atoms from the two deprotonated N-phthaloylglycine (Nphgly) ligands [systematic name: 2-(1,3-dioxo-2,3-di­hydro-1H-isoindol-2-yl)acetate] and two coordination water mol­ecules. In the crystal, O—H⋯O, C—H⋯O hydrogen bonds and π–π stacking inter­actions link the mol­ecules into the supra­molecular structure.
Citation

M. MAKOUF Naouel, (2019-01-25), "Diaquabis[4-(dimethylamino)pyridine-jN1]bis[2- (1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)acetatojO 1]cobalt(II)", [national] IUCrData , IUCrData

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2018-04-06

Carbon monoxide substitutions by trimethyl phosphite in diiron dithiolate complex: Fe-Fe bond cleavage, selectivity of the substitutions, crystal structures and electrochemical studies

The reaction of substitution of carbon monoxide by P(OMe)3 in the complex (m-h2PhC(S) ¼ C(S)Ph)
Fe2(CO)6 1 under thermal activation afforded two colored compounds: a binuclear disubstituted complex
(m-PhC(S) ¼ C(S)Ph)Fe2(CO)4 [P(OMe)3]2 2 and a mononuclear iron disubstituted complex
(h2PhC(S) ¼ C(S)Ph)Fe(CO)[P(OMe)3]2 3. Mass spectrometry, 1H NMR, IR and electrochemical studies
established that two (CO) have been substituted by P(OMe)3 in complexes 2 and 3. The X-ray studies
show that the two P(OMe)3 ligands are in apical positions in trans of the iron e iron bound of complex 2
and in equatorial positions in complex 3. However, the substitution reaction of (CO) by P(OMe)3 in
complex 1 under electron transfer catalysis (ETC) led to the monosubstituted compound (m-PhC(S) ¼ C(S)
Ph)Fe2(CO)5 [P(OMe)3] 4.
Citation

M. MAKOUF Naouel, (2018-04-06), "Carbon monoxide substitutions by trimethyl phosphite in diiron dithiolate complex: Fe-Fe bond cleavage, selectivity of the substitutions, crystal structures and electrochemical studies", [national] Journal of Organometallic Chemistry , Elsevier

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2009-12-09

Réaction de Remplacement de Carbonyles par P(OMe)3 dans le Complexe [µ-η2]1,2-(dithio)-1,2(diphenylethylene)-di-fer hexacarbonyle.

Substitution of carbon monoxide by trimethylphosphite in two diiron hexacarbonyl complexes of known structure has been studied using thermal activation or electron transfer catalysis.The reaction of substitution of the monoxide of carbon by P(OMe)3 in the complex (µ-η2PhC(S)=C(S)Ph)Fe2(CO)6 1 under thermal activation afforded two colored compounds: (η2PhC(S) =C(S) Ph) Fe (CO) [P (OMe) 3]2 2 and (µ-PhC(S) =C(S) Ph) Fe2 (CO) 4 [P (OMe) 3]2 3. Mass, 1HNMR and infrared spectral data are consistent with the structures of the complexes 2 and 3 determined by X-ray diffractometry.
Citation

M. MAKOUF Naouel, (2009-12-09), "Réaction de Remplacement de Carbonyles par P(OMe)3 dans le Complexe [µ-η2]1,2-(dithio)-1,2(diphenylethylene)-di-fer hexacarbonyle.", [international] VII èmes Journées Internationales de Chimie 7-9 Décembre 2009 , Université Mentouri Constantine, Algérie

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